熊联友,杨坤,孔巍,等. 5 t/d氢液化装置的研制[J]. 真空与低温,2024,30(4):349−354. DOI: 10.12446/j.issn.1006-7086.2024.04.001
引用本文: 熊联友,杨坤,孔巍,等. 5 t/d氢液化装置的研制[J]. 真空与低温,2024,30(4):349−354. DOI: 10.12446/j.issn.1006-7086.2024.04.001
XIONG L Y,YANG K,KONG W,et al. Development of a 5 t/d hydrogen liquefaction unit[J]. Vacuum and Cryogenics,2024,30(4):349−354. DOI: 10.12446/j.issn.1006-7086.2024.04.001
Citation: XIONG L Y,YANG K,KONG W,et al. Development of a 5 t/d hydrogen liquefaction unit[J]. Vacuum and Cryogenics,2024,30(4):349−354. DOI: 10.12446/j.issn.1006-7086.2024.04.001

5 t/d氢液化装置的研制

Development of a 5 t/d Hydrogen Liquefaction Unit

  • 摘要: 氢液化装置对于推动氢的大规模应用至关重要。介绍了中国首个5 t/d氢液化装置的技术特点及研发进程。该装置直接利用氢气作为制冷工质,采用带LN2预冷的双压克劳德氢气制冷循环来液化氢气,正-仲氢转化方式为80 K液氮温度下的等温转化结合80 K以下温区的连续正-仲氢转化,具有氢液化循环效率高、能耗低、正-仲氢转化效率高的优点。主要设备包括两个串级使用往复式无油氢压缩机、一个真空绝热冷箱(直径为3.2 m、长为11 m)及液氢储罐。其中真空绝热冷箱内的主要设备包括4台串联使用的氢气透平膨胀机、多级低温换热器、多级正仲氢转化器、低温控制阀门等。通过流程优化设计,该装置的氢液化能力为5 t/d,比能耗设计值为11 kW·h/kg。目前氢压缩机、氢液化冷箱已完成制造,即将进行系统调试及运行。

     

    Abstract: Hydrogen liquefaction plants are crucial for promoting the large-scale application of hydrogen. The technical features and development progress of the first 5 t/d hydrogen liquefaction unit in China are introduced. The hydrogen liquefaction unit directly uses hydrogen as a refrigerant, employing a dual-pressure Claude cycle with LN2 precooling to liquefy hydrogen. The ortho-para hydrogen conversion process is facilitated through a combination of isothermal conversion at 80 K using nitrogen as the cooling medium, and continuous ortho-para conversion at temperatures below 80 K. It provides the advantages of high hydrogen liquefaction cycle efficiency, low energy consumption, and high ortho-para conversion efficiency. The main equipment includes two sets of cascade reciprocating oil-free hydrogen compressor units, a vacuum insulated cold box with a diameter of 3.2 meters and a length of 11 meters, and a liquid hydrogen storage tank. The main equipment in the vacuum insulated cold box includes four hydrogen turbine expanders, multi-stage low-temperature heat exchangers, multi-stage ortho-para hydrogen converters, and low-temperature control valves. Through the process optimization design, the hydrogen liquefaction capacity is 5 t/d, and the designed specific energy consumption is 11 kW·h/kg. At present, the hydrogen compressors and hydrogen liquefaction cold box have been manufactured. The system commissioning and operation will be carried out soon.

     

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