基于CH3NH3PbI3-xClx钙钛矿的自滤波窄带光电探测器研究

Research on Self Filtering Narrowband Photodetector Based on CH3NH3PbI3-xClx Perovskite

  • 摘要: 窄带光电探测器在光通信、生物医学成像等高技术领域中有重要应用。然而,窄带探测器在探测范围、响应速度、暗电流等方面,仍不及性能卓越的真空探测器。通过调控离子掺杂浓度,成功制备了高质量的CH3NH3PbX3晶体,并在此基础上开发了高性能窄带光电探测器。实验结果表明:离子掺杂实现了波长范围的精确调控,半峰宽仅为18 nm;响应度达到106 mA/W,外量子效率最高可达26%,探测率为3.8×1010 \sqrt\mathrmc\mathrmm\cdot\mathrmH\mathrmz /W;在476~494 nm、526~544 nm、586~604 nm波段范围内实现了自滤波功能,达到了更精确的窄带光谱响应。该探测器在光通信、工业过程控制、安全检查及医疗成像领域具有广泛的应用潜力。

     

    Abstract: Narrowband photodetectors play a pivotal role in high-tech applications such as optical communication, biomedical imaging, and industrial sensing. However, current detectors have yet to outperform conventional vacuum detectors in terms of detection range, response speed, and dark current, primarily due to the environmental sensitivity and stability limitations of perovskite materials. This paper presents the fabrication and characterization of a self-filtering narrowband perovskite photodetector. By optimizing the surface morphology and grain size of perovskite films and exploiting the bandgap tunability of these materials, we demonstrate self-filtering capabilities in three specific wavelength ranges: 476~494 nm, 526~544 nm, and 586~604 nm. This innovation enables precise narrowband spectral responses essential for applications requiring high spectral selectivity. Systematic testing confirms significant performance enhancements within the target wavelength bands. The device achieves a responsivity of 106 mA/W, a twofold improvement in response speed, and a dark current reduction from 10 nA to 5 nA. These advancements directly address the limitations of current perovskite-based detectors. Comparative analysis shows that the self-filtering detector outperforms existing perovskite and vacuum photodetectors in terms of detection precision, response speed, and noise characteristics. Its high performance and self-filtering capabilities make it a promising candidate for applications in optical communication, industrial process control, safety inspection, and medical imaging. The proposed device not only overcomes the current bottlenecks of perovskite-based detectors but also paves the way for further advancements in narrowband photodetection technologies. This work underscores the potential of perovskite materials to revolutionize the photodetector industry and highlights the importance of continued research in this field.

     

/

返回文章
返回