阳极氧化法制备高品质TiO2纳米管光子晶体及其光子带隙调控研究

Preparation of High Qualith TiO2 Nanotube Photonic Crystal by Anodization and Its Photonic Band Gap Regulation

  • 摘要: 采用具有电压补偿机制的程控阳极氧化电压波形设计,成功制备出周期结构明显改善的高品质TiO2纳米管光子晶体。研究表明,适当的补偿电压能有效地解决在阳极氧化过程中因电流衰减导致TiO2纳米管光子晶体周期结构均匀性降低的难题,可使其光子带隙的品质明显提高;此外,通过对阳极氧化高低电压持续时间及反应过程中温度的调节,可实现对其光子带隙位置在可见光范围内的有效调控,并发现TiO2纳米管光子晶体的电子带隙宽度,随阳极氧化高电压持续时间的增加略有变宽,随电解液温度的升高而变窄。

     

    Abstract: High quality TiO2 nanotube photonic crystal with more uniform periodic structure was successfully prepared by improved anodization method with voltage compensation mechanism.The results showed that a suitable compensation voltage could effectively solve the problem of uneven periodic structure caused by the current attenuation in the preparation process for TiO2 nanotube photonic crystal,which is quite an improvement in quality of photonic bandgap.By adjusting the duration of high or low voltage and temperature,we could fulfill to regulate the position of the photonic bandgap within visible light range.Meanwhile,it was found that the electronic bandgap of the TiO2 nanotube photonic crystal was increased slightly with the increase of the duration of high voltage but it was narrowed slightly as the electrolyte temperature increased.

     

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