刘雪晴, 钟晓岚, 刁训刚. 氧化镍基电致变色薄膜与器件研究进展[J]. 真空与低温, 2020, 26(5): 345-360. DOI: 10.3969/j.issn.1006-7086.2020.05.001
引用本文: 刘雪晴, 钟晓岚, 刁训刚. 氧化镍基电致变色薄膜与器件研究进展[J]. 真空与低温, 2020, 26(5): 345-360. DOI: 10.3969/j.issn.1006-7086.2020.05.001
LIU Xueqing, ZHONG Xiaolan, DIAO Xungang. Advances in Electrochromic Films and Devices Based on Nickel Oxide[J]. VACUUM AND CRYOGENICS, 2020, 26(5): 345-360. DOI: 10.3969/j.issn.1006-7086.2020.05.001
Citation: LIU Xueqing, ZHONG Xiaolan, DIAO Xungang. Advances in Electrochromic Films and Devices Based on Nickel Oxide[J]. VACUUM AND CRYOGENICS, 2020, 26(5): 345-360. DOI: 10.3969/j.issn.1006-7086.2020.05.001

氧化镍基电致变色薄膜与器件研究进展

Advances in Electrochromic Films and Devices Based on Nickel Oxide

  • 摘要: 氧化镍(NiO)作为一种重要的无机电致变色材料,具有价格低廉、光学对比度大的优点,在智能窗等领域常作为互补型电致变色器件的阳极变色层。提高NiO薄膜的电致变色性能与循环稳定性是实现氧化镍基电致变色器件大规模应用的关键。本文从NiO薄膜的电致变色机制和制备方法入手,重点研究和总结了优化电致变色性能的几种手段,介绍了基于阳极电致变色材料NiO的电致变色器件,并就NiO薄膜电致变色的衰退机制和其对器件实际应用的限制进行了探讨,提出了提高器件循环寿命的有效措施,最后总结了氧化镍基电致变色器件的应用前景与发展趋势。

     

    Abstract: As an important inorganic electrochromic material,nickel oxide(NiO)is often used as the anode electrochromic layer of complementary electrochromic devices in smart windows and other fields,due to its great features such as low price and large optical contrasts.The key to the large-scale application of nickel oxide-based electrochromic devices is to improve electrochromic performance and cycle stability of NiO films.Therefore,this paper starts with the electrochromic mechanism and fabrication of NiO film,focuses on the methods to optimize the electrochromic properties of NiO film,then introduces the electrochromic devices based on the anode electrochromic material NiO,discusses the decay mechanisms that limit the practical application of electrochromic devices and presents effective measures to improve the cycle life of devices.Finally,the application prospect and development trends of nickel oxide-based electrochromic devices are summarized.

     

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