勾荣年, 尚伦霖, 曹学乾, 等. TiN/H-DLC薄膜的制备及其性能研究[J]. 真空与低温, 2021, 27(5): 430-438. DOI: 10.3969/j.issn.1006-7086.2021.05.004
引用本文: 勾荣年, 尚伦霖, 曹学乾, 等. TiN/H-DLC薄膜的制备及其性能研究[J]. 真空与低温, 2021, 27(5): 430-438. DOI: 10.3969/j.issn.1006-7086.2021.05.004
GOU Rongnian, SHANG Lunlin, CAO Xueqian, et al. Study on Preparation and Characterization of TiN/H-DLC Films[J]. VACUUM AND CRYOGENICS, 2021, 27(5): 430-438. DOI: 10.3969/j.issn.1006-7086.2021.05.004
Citation: GOU Rongnian, SHANG Lunlin, CAO Xueqian, et al. Study on Preparation and Characterization of TiN/H-DLC Films[J]. VACUUM AND CRYOGENICS, 2021, 27(5): 430-438. DOI: 10.3969/j.issn.1006-7086.2021.05.004

TiN/H-DLC薄膜的制备及其性能研究

Study on Preparation and Characterization of TiN/H-DLC Films

  • 摘要: 为了探究用复合技术制备的DLC复合薄膜的力学性能和耐腐蚀性能,采用多弧离子镀(MAIP)和非平衡磁控溅射技术(UBMS)分别在316L不锈钢基底上沉积了H-DLC、TiN和TiN/H-DLC薄膜。采用三维轮廓仪、扫描电镜以及拉曼光谱分析薄膜的形貌和微观结构,采用纳米压痕仪、划痕仪、CSM摩擦试验机和电化学工作站表征了薄膜的纳米硬度、膜基结合力、摩擦学性能和耐腐蚀性能。结果表明,用多弧离子镀引入TiN层能够有效提高TiN/H-DLC复合薄膜的结合力并降低摩擦因数,但是薄膜的磨损率未明显降低,其原因可能是表面粗糙度的影响;H-DLC薄膜表面较为致密,在3.5%NaCl溶液中具有较好的耐腐蚀性能。复合制备技术可改善TiN/H-DLC薄膜的力学性能和特定环境下的耐腐蚀性能。

     

    Abstract: In order to explore the mechanical properties and corrosion resistance of DLC composite film prepared by Duplex deposition technology.TiN/H-DLC film was deposited on 316L stainless steel substrate by multi-arc ion plating(MAIP)and unbalanced magnetron sputtering(UBMS).The morphology and microstructure of the films were characterized by three-dimensional profiler,scanning electron microscope and Raman Spectroscopy.The hardness,adhesion,tribological properties and corrosion resistance of above film were characterized by nanoindenter,scratch tester,CSM tribometer and electrochemical workstation,respectively.Results show that the introduction of the TiN layer improved the adhesion between film and substrate,and reduced the friction coefficient of TiN/H-DLC composite film.But it did not effectively reduce the wear rate,which may be due to the fact that the roughness is the main factor affecting wear rate in the case of close hardness and friction coefficient.In addition,the H-DLC surface is relatively dense,thus obtaining the best corrosion resistance in 3.5% NaCl.Therefore,the use of duplex deposition technology can enhance the mechanical proper-ties of H-DLC film.

     

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