刘瑞姿, 王杰, 董长昆. 基于气体吸附的碳纳米管场发射氦气传感技术研究[J]. 真空与低温, 2022, 28(4): 432-437. DOI: 10.3969/j.issn.1006-7086.2022.04.008
引用本文: 刘瑞姿, 王杰, 董长昆. 基于气体吸附的碳纳米管场发射氦气传感技术研究[J]. 真空与低温, 2022, 28(4): 432-437. DOI: 10.3969/j.issn.1006-7086.2022.04.008
LIU Ruizi, WANG Jie, DONG Changkun. Carbon Nanotube Field Emission Helium Sensing Technology Based on Gas Adsorption[J]. VACUUM AND CRYOGENICS, 2022, 28(4): 432-437. DOI: 10.3969/j.issn.1006-7086.2022.04.008
Citation: LIU Ruizi, WANG Jie, DONG Changkun. Carbon Nanotube Field Emission Helium Sensing Technology Based on Gas Adsorption[J]. VACUUM AND CRYOGENICS, 2022, 28(4): 432-437. DOI: 10.3969/j.issn.1006-7086.2022.04.008

基于气体吸附的碳纳米管场发射氦气传感技术研究

Carbon Nanotube Field Emission Helium Sensing Technology Based on Gas Adsorption

  • 摘要: 氦气分压测量在检漏技术、液氦装置质量监控等方面具有重要的应用价值。基于气体吸附的碳纳米管场发射阴极小电流发射增强效应,开发了低压He压力传感技术。采用热化学气相沉积法(HCVD)在镍合金基底上制备了多壁碳纳米管(MWNT)薄膜样品,利用二极式结构对MWNT薄膜阴极的场发射与传感性能进行了研究。结果显示,在10-7~10-3Pa区间,部分样品的场发射电流随着真空系统He压力的升高而增大,呈现He压力传感效应。对大量样品的测试发现,晶体性差(ID/IG≥0.9)的MWNT薄膜阴极对He有强烈的传感特性。第一性原理研究表明:He吸附在MWNTs的缺陷部位后,电荷的转移以及聚集效应是MWNT薄膜阴极产生He压力传感效应的关键因素。该传感技术具有开发为微型氦气检漏与分压力测量器件的潜力。

     

    Abstract: Helium partial pressure measurement is important for the leak detection and quality control of liquid helium equipment.In this work,based on small current emission enhancement effect of MWNTs field emission cathode from gas adsorption,the low pressure He sensing technique was developed.Multi-walled carbon nanotube(MWNT)films were grown directly on nickel alloy substrates by thermal chemical vapor deposition(CVD).Field emission and sensing performance were tested in diode structures.The results showed that in 10-7to 10-3Pa range the field emission currents increase with increasing He pressures for some MWNT samples,exhibiting good He sensing behaviors.The experiments for a large number of MWNT samples showed that MWNTs with poor crystallinity(ID/IG≥0.9)behaved strong He sensing properties.The first-principles study revealed that the charge transfer and aggregation is the key factors of helium pressure sensing effect generated by MWNT cathode after helium adsorption at the defeet location.This technique is promising to develop miniature He leak detection and partial pressure measurement devices.

     

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