刘思彤, 张钦睿, 郑宇亭, 等. SiNx介质薄膜制备及其对GaN表面金刚石形核生长的影响[J]. 真空与低温, 2023, 29(1): 12-19. DOI: 10.3969/j.issn.1006-7086.2023.01.003
引用本文: 刘思彤, 张钦睿, 郑宇亭, 等. SiNx介质薄膜制备及其对GaN表面金刚石形核生长的影响[J]. 真空与低温, 2023, 29(1): 12-19. DOI: 10.3969/j.issn.1006-7086.2023.01.003
LIU Sitong, ZHANG Qinrui, Zheng Yuting, et al. Preparation of SiNx Dielectric Film and Its Effect on Diamond Nucleation Growth on GaN Surface[J]. VACUUM AND CRYOGENICS, 2023, 29(1): 12-19. DOI: 10.3969/j.issn.1006-7086.2023.01.003
Citation: LIU Sitong, ZHANG Qinrui, Zheng Yuting, et al. Preparation of SiNx Dielectric Film and Its Effect on Diamond Nucleation Growth on GaN Surface[J]. VACUUM AND CRYOGENICS, 2023, 29(1): 12-19. DOI: 10.3969/j.issn.1006-7086.2023.01.003

SiNx介质薄膜制备及其对GaN表面金刚石形核生长的影响

Preparation of SiNx Dielectric Film and Its Effect on Diamond Nucleation Growth on GaN Surface

  • 摘要: SiNx作为GaN和金刚石异质结构的中间层,不仅是下层GaN材料的保护层,也是上层金刚石的形核生长层,因此SiNx介质薄膜对于GaN表面合成高质量金刚石具有重要的意义。研究分别采用低压化学气相沉积(LPCVD)和磁控溅射(MS)方法在GaN-Si衬底上制备SiNx介质薄膜。利用扫描电镜、傅立叶红光光谱、X射线衍射、激光拉曼等技术对SiNx薄膜的表面形貌、晶体结构和表面官能团等进行分析。结果表明,采用LPCVD镀制的非晶态SiNx介质薄膜经籽晶播种、形核生长金刚石后,金刚石/SiNx/GaN界面完整致密;采用MS制备的SiNx介质薄膜呈晶态特征,对应的界面出现明显的刻蚀坑。沉积方式会影响SiNx薄膜的晶体结构和微观形貌,高致密度的非晶态结构有利于金刚石层快速形核生长,对于构建金刚石基GaN结构更为有利。

     

    Abstract: As the intermediate layer between GaN and diamond heterostructures, SiNx is not only the protective layer of the underlying GaN material, but also the nucleation and growth layer of the upper diamond.Therefore, the SiNx dielec-tric layer is of great significance for synthesizing high-quality diamond on the GaN surface.The research uses low pres-sure chemical vapor deposition(LPCVD) and magnetron sputtering(MS) methods to prepare silicon nitride dielectric layers on silicon-based gallium nitride substrates.Analyses of the surface morphology, crystal structure, and surface func-tional groups of SiNx films were performed using scanning electron microscopy, Fourier transform red spectroscopy, X-ray diffraction, and laser Raman spectroscopy.The results show that the diamond/gallium nitride interface is complete and dense after seed crystal seeding and diamond nucleation in the amorphous silicon nitride dielectric layer plated by LPCVD, while the dielectric layer prepared by magnetron has crystalline characteristics., the corresponding interface will have obvious etching pits.The deposition method of the dielectric layer will affect the crystal structure and microscopic morphology of the SiNx film.The high-density amorphous structure is more conducive to the rapid nucleation and growth of the diamond layer, which is more favorable for the construction of GaN-on-diamond structures.

     

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