闫巨擘, 赖振国, 唐诗琪, 等. 氮含量对(BCSiAlCr)Nx薄膜结构和耐腐蚀性能的影响[J]. 真空与低温, 2023, 29(1): 28-35. DOI: 10.3969/j.issn.1006-7086.2023.01.005
引用本文: 闫巨擘, 赖振国, 唐诗琪, 等. 氮含量对(BCSiAlCr)Nx薄膜结构和耐腐蚀性能的影响[J]. 真空与低温, 2023, 29(1): 28-35. DOI: 10.3969/j.issn.1006-7086.2023.01.005
YAN Jubo, LAI Zhenguo, TANG Shiqi, et al. Effect of Nitrogen Content on Structure and Corrosion Resistance of(BCSiAlCr)Nx Film[J]. VACUUM AND CRYOGENICS, 2023, 29(1): 28-35. DOI: 10.3969/j.issn.1006-7086.2023.01.005
Citation: YAN Jubo, LAI Zhenguo, TANG Shiqi, et al. Effect of Nitrogen Content on Structure and Corrosion Resistance of(BCSiAlCr)Nx Film[J]. VACUUM AND CRYOGENICS, 2023, 29(1): 28-35. DOI: 10.3969/j.issn.1006-7086.2023.01.005

氮含量对(BCSiAlCr)Nx薄膜结构和耐腐蚀性能的影响

Effect of Nitrogen Content on Structure and Corrosion Resistance of(BCSiAlCr)Nx Film

  • 摘要: 采用直流磁控溅射技术在Si(100)晶片和304不锈钢上沉积了(BCSiAlCr)Nx薄膜。采用XRD、XPS、TEM和SEM分别分析了薄膜的成分、晶体结构和形貌。利用电化学工作站测试了薄膜的耐腐蚀性能,包括动电位极化试验、恒电位极化试验以及阻抗试验。结果表明,在3.5% NaCl溶液中HE3薄膜样品具有最低的腐蚀电流密度(Icorr)0.031 1 μA/cm2和最高的腐蚀电位-37.557 mV;在0.5 mol/L硫酸溶液耐腐蚀试验中,HE3薄膜样品同样具有最低的腐蚀电流密度和最高的腐蚀电位,表现出最优异的耐腐蚀性能。随着薄膜中氮含量的增多,薄膜非晶程度增加,致密性提高,表面缺陷及孔洞消失,耐腐蚀性能改善。研究结果证明,(BCSiAlCr)Nx薄膜在腐蚀防护方面具有潜在的应用前景。

     

    Abstract: A(BCSiAlCr) Nx films were deposited on the Si(100) wafer and 304 stainless steel using DC magnetron sputtering technology.XRD, XPS, TEM and SEM were used to analyze the composition, crystal structure and topography of the film, respectively.The corrosion resistance of the film was tested by electrochemical workstation, including potentio-dynamic polarization experiment, potentiostatic polarization experiment and impedance experiment.The experimental re-sults show that in 3.5% NaCl solution, compared with 304 stainless steel, HE3 film has the lowest corrosion current density(Icorr) of 0.031 1 μA/cm2, and the highest corrosion potential of-37.557 mV.Meanwhile, in the corrosion resistance test of 0.5 mol/L sulfuric acid solution, HE3 film also has the lowest corrosion current density and the highest corrosion potential, showing the most excellent corrosion resistance.This is mainly due to the increase of nitrogen content in film, the amor-phous degree of film increases, the thin film becomes denser, surface defects and cavities disappear, which effectively im-proves the corrosion resistance of film.(BCSiAlCr) Nx films have potential application prospects in corrosion protection.

     

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